PI-METHYL INTERACTIONS AND P-TERT-BUTYLCALIX[4]ARENE-GUEST STABILITY - NMR AND CRYSTALLOGRAPHIC STUDIES OF CYCLOHEXANE AND N-PENTANE INCLUSION-COMPOUNDS

Authors
BROUWER EB ENRIGHT GD RIPMEESTER JA
Citation
Eb. Brouwer et al., PI-METHYL INTERACTIONS AND P-TERT-BUTYLCALIX[4]ARENE-GUEST STABILITY - NMR AND CRYSTALLOGRAPHIC STUDIES OF CYCLOHEXANE AND N-PENTANE INCLUSION-COMPOUNDS, Supramolecular chemistry, 7(2), 1996, pp. 143-145
Citations number
14
Categorie Soggetti
Chemistry
Journal title
Supramolecular chemistry → ACNP
ISSN journal
10610278
Volume
7
Issue
2
Year of publication
1996
Pages
143 - 145
Database
ISI
SICI code
1061-0278(1996)7:2<143:PIAPS->2.0.ZU;2-8
Abstract
Despite the absence of pi(guest)-methyl(host) interactions, p-tert-but ylcalix[4]arene-cyclohexane [C12.5H17O, tetragonal, P 4n, a = 12.9446( 4), c = 12.8156(4) Angstrom, D-c = 1.134 g cm(-3), Z = 8, 1697 observe d data I > 2.5 sigma(I), R = 0.054] and p-tert-butylcalix[4]arene-n-pe ntane [C12.25H17O, tetragonal, P 4n, a = 13.0230(19), c = 12.6190(12) Angstrom, D-c = 1.119 g cm(-3), Z = 8, 1641 observed data I > 2.5 sigm a(I), R = 0.048], characterized by NMR and X-ray diffraction, are stab le and isoluble compounds.