Tl2Ba2Ca2Cu3Ox (TBCCO) thin films with T-c greater than or equal to 11
0 K were grown on the yttrium-stabilized (100) zirconia (YSZ) substrat
es by d.c. magnetron sputtering technique. The d.c.-SQUIDS made from t
he TBCCO films have operated at temperatures near 100 K. The relations
hip between I-c and T of the grain boundary junctions is I proportiona
l to (1 - T/T-c)(n), with n approximate to 1.6. This indicates that th
ey are the long bridge junctions. The SQUIDs were biased by d.c. curre
nts. Meanwhile, a 25 kHz ac. flux with a peak-to-peak amplitude of phi
(0) was applied through a modulation coil. The voltage across the SQUI
D was amplified by a factor of about 10,000 with a cooled transformer
and a preamplifier. Our investigation showed that the d.c.-SQUIDs can
operate near 100 K; some of them can even operate at 105 K.