1ST CHARACTERIZATION OF A TETRATHIOMOLYBDATE(V) DERIVATIVE BY EPR, UV-VIS AND IR SPECTROELECTROCHEMISTRY

Authors
SCHAFER R FIEDLER J MOSCHEROSCH M KAIM W
Citation
R. Schafer et al., 1ST CHARACTERIZATION OF A TETRATHIOMOLYBDATE(V) DERIVATIVE BY EPR, UV-VIS AND IR SPECTROELECTROCHEMISTRY, Journal of the Chemical Society, Chemical Communications, (11), 1993, pp. 896-897
Citations number
16
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
11
Year of publication
1993
Pages
896 - 897
Database
ISI
SICI code
0022-4936(1993):11<896:1COATD>2.0.ZU;2-I
Abstract
The trinuclear complex ion [(NC)(OC)3Re(MoS4)Re(CO)3(CN)]2- 1(2-) is r eversibly reduced to a Mo(V) containing trianion 1(3-), which exhibits hypsochromically shifted charge-transfer bands, bathochromically shif ted CN, CO and MoS stretching frequencies and an axial EPR signal with g(parallel-to) > g(perpendicular-to).