ISOLATION OF A SINGLE-INSERTION INTERMEDIATE IN THE CATALYTIC POLYMERIZATION OF PROPENE BY A CATIONIC TRIS(HYDROCARBYL) ZIRCONIUM COMPLEX

Authors
PELLECCHIA C GRASSI A ZAMBELLI A
Citation
C. Pellecchia et al., ISOLATION OF A SINGLE-INSERTION INTERMEDIATE IN THE CATALYTIC POLYMERIZATION OF PROPENE BY A CATIONIC TRIS(HYDROCARBYL) ZIRCONIUM COMPLEX, Journal of the Chemical Society, Chemical Communications, (11), 1993, pp. 947-949
Citations number
41
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
11
Year of publication
1993
Pages
947 - 949
Database
ISI
SICI code
0022-4936(1993):11<947:IOASII>2.0.ZU;2-8
Abstract
Propene reacts smoothly with the alkene polymerization catalyst [Zr(CH 2Ph)3{(eta6-PhCH2)B(C6F5)3)] 1 to give initially the single-insertion adduct r(eta(n)-CH2Ph)2(CH2CHMeCH2Ph)]+[B(CH2Ph)(C6F5)3]- 2, which has been isolated and characterized.