SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF THE MIXED LITHIUM MAGNESIUM AMIDE, [(PHCH2(ME2NCH2CH2)N)4LI2MG] - A NEW-TYPE OF MAGNESIATE COMPLEX FREE OF A DONOR SOLVENT AS LIGAND

Authors
CLEGG W HENDERSON KW MULVEY RE ONEIL PA
Citation
W. Clegg et al., SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF THE MIXED LITHIUM MAGNESIUM AMIDE, [(PHCH2(ME2NCH2CH2)N)4LI2MG] - A NEW-TYPE OF MAGNESIATE COMPLEX FREE OF A DONOR SOLVENT AS LIGAND, Journal of the Chemical Society, Chemical Communications, (11), 1993, pp. 969-970
Citations number
12
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
11
Year of publication
1993
Pages
969 - 970
Database
ISI
SICI code
0022-4936(1993):11<969:SASCOT>2.0.ZU;2-N
Abstract
A mixture of the alkyl(amido)magnesium compound, [PhCH2(Me2NCH2CH2)NMg Bun], the secondary amine, [PhCH2(Me2NCH2CH2)NH], and the alkyl lithiu m, (Bu(n)Li), produces the lithium amidomagnesiate, [{PhCH2(Me2NCH2CH2 )N}4Li2Mg] which is shown by an X-ray diffraction study to have intram olecular (tertiary amine) N-Li coordinations in the solid state.