We consider the influence on plasma recombination of the formation of
negative and molecular ions in a divertor plasma. We take into account
different atomic processes (vibrational excitation of molecular hydro
gen, electron dissociative attachment, ion conversion, charge exchange
and dissociative recombinations, dissociation and ionization, etc.) a
nd find the expression for the effective plasma recombination rate con
stant from a suitably reduced set of coupled rate equations. We estima
te the influence of the recombination process on divertor plasma behav
ior and find that for AlcatorC-MOD-like parameters plasma recombinatio
n due to negative and molecular ions becomes significant in the temper
ature range below a few eV. We conclude that plasma recombination is a
strongly contributing mechanism for the explanation of divertor plasm
a detachment in low temperature plasmas.