Jl. Moranlopez et Jm. Sanchez, THE PHASE-DIAGRAM OF OXYGEN ORDERING IN YBA2CU3O6- THE 9-POINT CLUSTER APPROXIMATION(DELTA ), Physica. C, Superconductivity, 210(3-4), 1993, pp. 401-407
The thermodynamics of oxygen ordering in the basal plane of YBa2Cu3O6delta is studied within the nine point approximation of the cluster va
riation method. The phenomena is modeled by an Ising model with neares
t- and next-nearest-neighbor interactions. The composition (delta) ver
sus the temperature (T) phase diagram is calculated and compared with
results obtained by using smaller clusters and the Monte Carlo method.
The composition dependence of the order parameters for various temper
atures is also presented.