A CONVENIENT SYNTHESIS OF PROTECTED AND FREE HOMOALLYLIC ALCOHOLS - CATALYTIC USE OF DIBUTYLTIN DICHLORIDE IN THE ALLYLATION OF ALDEHYDES WITH ALLYLTRIBUTYLTIN

Authors
WHITESELL JK APODACA R
Citation
Jk. Whitesell et R. Apodaca, A CONVENIENT SYNTHESIS OF PROTECTED AND FREE HOMOALLYLIC ALCOHOLS - CATALYTIC USE OF DIBUTYLTIN DICHLORIDE IN THE ALLYLATION OF ALDEHYDES WITH ALLYLTRIBUTYLTIN, Tetrahedron letters, 37(23), 1996, pp. 3955-3958
Citations number
21
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
37
Issue
23
Year of publication
1996
Pages
3955 - 3958
Database
ISI
SICI code
0040-4039(1996)37:23<3955:ACSOPA>2.0.ZU;2-4
Abstract
A new procedure for the allylation of aldehydes with allyltributyltin in the presence of 10 mol% dibutyltin dichloride and either an acid ch loride or trimethylsilyl chloride has been developed. Homoallylic este rs, carbonates, trimethylsilyl ethers, and alcohols were obtained in u p to 99% yield. (C) 1996 Elsevier Science Ltd