OPTICALLY-ACTIVE SULFOXIMINES IN ENANTIOSELECTIVE PALLADIUM CATALYSIS

Authors
BOLM C KAUFMANN D ZEHNDER M NEUBURGER M
Citation
C. Bolm et al., OPTICALLY-ACTIVE SULFOXIMINES IN ENANTIOSELECTIVE PALLADIUM CATALYSIS, Tetrahedron letters, 37(23), 1996, pp. 3985-3988
Citations number
48
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
37
Issue
23
Year of publication
1996
Pages
3985 - 3988
Database
ISI
SICI code
0040-4039(1996)37:23<3985:OSIEPC>2.0.ZU;2-4
Abstract
Chiral sulfoximine/Pd-complexes catalyze enantioselective allylic alky lations. The corresponding products have been obtained in good yields with moderate enantioselectivities (up to 73% ee). The crystal structu re of an allyl/Pd(II)-complex bearing a chelating sulfoximine is repor ted. (C) 1996 Elsevier Science Ltd