The electronic structure of the V(100) surface has been studied by mea
ns of angularly resolved photoelectron spectroscopy (ARUPS) and moment
um- (k-) resolved inverse photoemission spectroscopy (KRIPES). A narro
w peak in the photoemission spectrum which is seen at the Fermi level
is attributed to a transition from a surface resonance. The existence
of this surface resonance at the Fermi level of the V(100) surface is
potentially very important for the occurrence of the expected magnetic
ordering of this surface. The energy of the critical point H-25', whi
ch defines the top of the unoccupied part of the 3d band, has been det
ermined to be within 3.0-3.2 eV above E(F) from the normal incidence K
RIPES spectra.