T. Antonic et al., DISSOLUTION OF AMORPHOUS ALUMINOSILICATE ZEOLITE PRECURSORS IN ALKALINE-SOLUTIONS .1. KINETICS OF THE DISSOLUTION, Journal of the Chemical Society. Faraday transactions, 89(11), 1993, pp. 1817-1822
Citations number
30
Categorie Soggetti
Chemistry Physical","Physics, Atomic, Molecular & Chemical
The kinetics of dissolution of differently prepared amorphous aluminos
ilicate precursors having various Si : Al molar ratios have been studi
ed by measuring the change in the aluminium and silicon concentrations
in the liquid phase as well as the change in the degree of Si polycon
densation in the liquid phase during the dissolution in 0.2 mol dm-3 N
aOH solution at 80-degrees-C. Applying different kinetic equations for
the analysis of the experimental results, it was found that the rate
of dissolution of all the solids examined can be described by a modifi
ed Nernst's equation. The mechanism of dissolution was also considered
.