DISSOLUTION OF AMORPHOUS ALUMINOSILICATE ZEOLITE PRECURSORS IN ALKALINE-SOLUTIONS .1. KINETICS OF THE DISSOLUTION

Citation
T. Antonic et al., DISSOLUTION OF AMORPHOUS ALUMINOSILICATE ZEOLITE PRECURSORS IN ALKALINE-SOLUTIONS .1. KINETICS OF THE DISSOLUTION, Journal of the Chemical Society. Faraday transactions, 89(11), 1993, pp. 1817-1822
Citations number
30
Categorie Soggetti
Chemistry Physical","Physics, Atomic, Molecular & Chemical
ISSN journal
09565000
Volume
89
Issue
11
Year of publication
1993
Pages
1817 - 1822
Database
ISI
SICI code
0956-5000(1993)89:11<1817:DOAAZP>2.0.ZU;2-T
Abstract
The kinetics of dissolution of differently prepared amorphous aluminos ilicate precursors having various Si : Al molar ratios have been studi ed by measuring the change in the aluminium and silicon concentrations in the liquid phase as well as the change in the degree of Si polycon densation in the liquid phase during the dissolution in 0.2 mol dm-3 N aOH solution at 80-degrees-C. Applying different kinetic equations for the analysis of the experimental results, it was found that the rate of dissolution of all the solids examined can be described by a modifi ed Nernst's equation. The mechanism of dissolution was also considered .