Pi. Mitchell et al., THE 3S(2)3P(3) S-4-]3S3P(3)(S-5)NP P-4 TRANSITIONS IN ATOMIC PHOSPHORUS, Journal of physics. B, Atomic molecular and optical physics, 29(11), 1996, pp. 411-413
The photoabsorption spectrum of atomic phosphorus has been recorded in
the 140-600 Angstrom region. The Beutler-Fano profiles due to autoion
izing 3s(2)3p(3 4)S --> 3s3p(3)(S-5)np P-4 (5 less than or equal to n
less than or equal to 14) transitions have been observed and fitted to
a Rydberg series. Calculations made with the Cowan code show that int
eraction with the 3p(-2)3d4p (also written as 3s(2)3p3d4p) configurati
on is negligible, unlike the situation for 3s photoexcitation in Ar I.