MOLECULAR PHOTOIONIZATION AS A PROBE OF VIBRATIONAL-ROTATIONAL-ELECTRONIC CORRELATIONS

Authors
RAO RM POLIAKOFF ED WANG KH MCKOY V
Citation
Rm. Rao et al., MOLECULAR PHOTOIONIZATION AS A PROBE OF VIBRATIONAL-ROTATIONAL-ELECTRONIC CORRELATIONS, The Journal of chemical physics, 104(23), 1996, pp. 9654-9657
Citations number
28
Categorie Soggetti
Physics, Atomic, Molecular & Chemical
Journal title
The Journal of chemical physics → ACNP
ISSN journal
00219606
Volume
104
Issue
23
Year of publication
1996
Pages
9654 - 9657
Database
ISI
SICI code
0021-9606(1996)104:23<9654:MPAAPO>2.0.ZU;2-#
Abstract
We determine the rotationally state-resolved 2 sigma(u)(-1) photoioniz ation of N-2 into alternative vibrational channels as a function of en ergy over a 200 eV range. Experiment and theory reveal that Cooper min ima highlight the coupling between electronic, vibrational, and rotati onal degrees of freedom over this very wide range.