S. Szymura et al., MICROSTRUCTURE, MAGNETIC-PROPERTIES, AND CORROSION BEHAVIOR OF THE COPPER-DOPED ND-FE-B SINTERED MAGNETS, Physica status solidi. a, Applied research, 137(1), 1993, pp. 179-188
The effect of Cu addition to the three-component Nd-Fe-B sintered perm
anent magnet on the phase structure, magnetic properties. and corrosio
n behaviour is analyzed. It is found that this addition changes the co
mposition of the grain-boundary Nd-rich phase to NdCu2. NdFe, and eute
ctic phases. The latter two phases deteriorate the hard magnetic prope
rties due to a decrease of isolation and decoupling of the Nd2Fe14B gr
ains and a decrease of the volume fraction of the hard magnetic Nd2Fe1
4B phase. The corrosion resistance of the Nd-Fe-B magnet in acid solut
ion and under conditions corresponding to the industrial atmosphere is
improved by addition of this element.