SYNTHESIS AND X-RAY CRYSTAL-STRUCTURE OF A NOVEL ZINC ATE COMPLEX, [LI(TMEDA)]ZN-2(CH(2)SIME(2)SIME(2)CH(2))(2)

Authors
WYRWA R FROHLICH HO GORLS H
Citation
R. Wyrwa et al., SYNTHESIS AND X-RAY CRYSTAL-STRUCTURE OF A NOVEL ZINC ATE COMPLEX, [LI(TMEDA)]ZN-2(CH(2)SIME(2)SIME(2)CH(2))(2), Organometallics, 15(12), 1996, pp. 2833-2835
Citations number
27
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
15
Issue
12
Year of publication
1996
Pages
2833 - 2835
Database
ISI
SICI code
0276-7333(1996)15:12<2833:SAXCOA>2.0.ZU;2-F
Abstract
[Li(TMEDA)]Zn-2(CH(2)SiMe(2)SiMe(2)CH(2))(2) (6) (TMEDA = (CH3)(2)NCH2 CH2N(CH3)(2)) was obtained in 70% yield by a one-pot reaction of ClCH( 2)SiMe(2)SiMe(2)CH(2)Cl, ZnCl2, and lithium sodium alloy in diethyl et her. DTA investigations of the complex showed that thermal decompositi on takes place at 148 degrees C; the molecular structure of 6 has been established by X-ray structure analysis.