Ablation of carbon clusters from a graphite surface exposed to 35 ps w
ide 1064 nm wavelength, laser pulses of intensities of the order of 10
(14) W cm(-2) yields cluster ions in high charge states. Double and tr
iple coincidence spectra of singly-charged atomic fragments resulting
from spontaneous dissociation of C-n(q+) ions yield evidence that the
kinetic energies released are much less than those calculated using ab
intio configuration interaction methods.