A. Venugopal et al., EFFECT OF GRAIN-BOUNDARY CORROSION ON IMPEDANCE CHARACTERISTICS OF ANALUMINUM-ZINC-INDIUM ALLOY IN 3.5-PERCENT SODIUM-CHLORIDE SOLUTION, Corrosion, 52(2), 1996, pp. 138-142
Electrochemical impedance spectroscopy (EIS) was used to understand th
e dissolution behavior of an Al-Zn-In alloy in 3.5% sodium chloride (N
aCl) solution as a function of time after the alloy was subjected to g
alvanostatic dissolution. Compared to optical microscopy, the changing
trend in impedance spectra reflected the preferential dissolution of
the alloy along the grain boundaries, The usefulness of EIS as a tool
to indicate the current efficiency loss from grain-boundary attack was
illustrated.