Although impurity diffusion values are of great interest in developing
nickel base super alloys, limited data in 4d-transition elements are
available. This paper reports on niobium diffusion data in nickel in t
he temperature range between 1200 and 1500 K, obtained by using an ele
ctron probe microanalyser. The temperature dependence of the diffusion
coefficient, D-Nb, can be expressed by the following Arrhenius relati
on, D-Nb = 1.04(-0.48)(+0.87) X 10(-6) exp[-(202.59 +/- 4.71 -0.48 kJ/
mol)/RT] m(2)/s. These studies have shown that the niobium diffusivity
is nearly one order of magnitude higher than the self diffusivity in
nickel. The large difference between the activation energy values (Del
ta Q = -78.31 kJ/mol) indicates a rather high impurity-vacancy binding
energy.