Sm. Kulikov et al., USE OF ELECTROMEMBRANE TECHNOLOGY FOR WASTE-WATER TREATMENT AND MODERN ACIDIC CATALYST SYNTHESIS, Desalination, 104(1-2), 1996, pp. 107-111
The use of electromembrane technology for aluminium plant waste water
treatment and for a new type of acidic catalyst synthesis has been stu
died. To recycle the exhaust gas desulphurization solution of an alumi
nium plant whose main components were Na2SO4 and NaF the four-compartm
ent electrodialyzer with one cation exchange and two anion exchange me
mbranes was used. Desalination and recycling of this solution with sim
ultaneous formation of caustic soda and AlF3 used in the main process
is an example of waste water recycling. For tungstic heteropoly acid s
ynthesis from sodium tungstate and phosphate the traditional two-compa
rtment electrodialyzer with a cation exchange membrane was used. Elect
rochemical acidification of substrates in the anode compartment of the
electrodialyzer with simultaneous removal of sodium ions through the
membrane permits a quantitative yield of the product and excludes wast
e water formation.