THERMAL-STABILITY OF NICKEL-COMPLEXES FORMED WITH PHENYLAZOTHIOALKYLCARBOXIMIDES IN VARIOUS SOLVENTS

Citation
Md. Revenco et al., THERMAL-STABILITY OF NICKEL-COMPLEXES FORMED WITH PHENYLAZOTHIOALKYLCARBOXIMIDES IN VARIOUS SOLVENTS, Thermochimica acta, 276, 1996, pp. 79-90
Citations number
11
Categorie Soggetti
Chemistry Analytical
Journal title
ISSN journal
00406031
Volume
276
Year of publication
1996
Pages
79 - 90
Database
ISI
SICI code
0040-6031(1996)276:<79:TONFWP>2.0.ZU;2-V
Abstract
Thermogravimetric TG/DTG and calorimetric DSC studies of four types of complexes: (A) Ni(RL)(2)I-2 . 2S, (B) Ni(RL)(2)I-2 . S, (C) Ni(RL)(2) I-2, and (D) Ni(RL)(2)(I-3)(2) were performed. The decomposition steps of these compounds were observed. The important role of the solvent m olecules S in stabilization of the crystal structure of the examined c omplexes is suggested.