Asteroids and comets that are vaporized during hypervelocity impact ev
ents can inject large masses of S into the stratosphere where it can p
otentially affect the radiation budget of the Earth, alter the chemist
ry of the ozone layer, and eventually be converted to sulfuric acid ra
in. Relatively small carbonaceous asteroids, 0.3 km in diameter, conta
in 5 times more S than the entire modern stratosphere and these object
s hit the Earth at an average rate of 1 per 10,000 years. Larger impac
t events, capable of injecting 10(15) g of S into the stratosphere, oc
cur at an average rate of 1 per 1 million years. Calculations indicate
there is sufficient O and H in the vapor plumes of most impact events
to convert the S to sulfuric acid aerosols. If this conversion occurs
, then the larger impact events could depress mean surface temperature
s by more than 2 degrees C for 3 years or longer.