We have used high-energy inelastic neutron scattering to detect optica
l magnons directly in antiferromagnetic YBa2Cu3O6.2. The optical magno
n gap is 67+/-5 meV. This implies an intrabilayer superexchange consta
nt perpendicular to the CuO2 layers of J(perpendicular to) = 0.08 J(pa
rallel to) where J(parallel to) is the in-plane nearest-neighbor super
exchange constant.