M. Fally et al., HEAT-DIFFUSION CENTRAL PEAK IN THE DIELECTRIC SUSCEPTIBILITY OF FERROELECTRIC MATERIALS, Physical review. B, Condensed matter, 53(22), 1996, pp. 14769-14772
Recently, low-frequency measurements (0.1-Hz region) of the elastic su
sceptibility in KSCN near the order disorder phase transition at T-c=4
10 K revealed a relaxation that could be explained by entropy fluctuat
ions. We present a phenomenological theory describing the heat-diffusi
on central peak in the macroscopic (q=0) dielectric susceptibility. It
results from the Landau free energy and the heat-diffusion equation.
The model predicts a relaxation in the ferroelectric phase at low freq
uencies that depends on sample size. It does not follow a simple Debye
behavior, but reveals a long high-frequency tail.