The use of microwave energy to produce high temperatures to sinter cer
amics, appears as a solution of great interest ( economical in time an
d cost, ecological, and may lead to materials with new properties). Ho
wever, the microwave-matter interactions are very complicated and the
use of microwave is generally limited to the laboratory stage. This pa
per deals with the results obtained when sintering a set of materials
( materials with different conductivities i.e. insulating, semiconduct
ing and conducting materials) in a TE102 microwave cavity. It demonstr
ates that the heating is strongly related to the conducting properties
. So, a crossover betwen the dielectric heating and the magnetic induc
tion heating appears when the electrical conductivity is close to 10(-
1) Omega(-1) cm(-1).