K3BISE3, RB3BISE3, AND CS3BISE3 - DERIVAT IVES OF THE TH3P4 STRUCTURETYPE

Authors
BRONGER W DONIKE A SCHMITZ D
Citation
W. Bronger et al., K3BISE3, RB3BISE3, AND CS3BISE3 - DERIVAT IVES OF THE TH3P4 STRUCTURETYPE, Zeitschrift fur anorganische und allgemeine Chemie, 622(6), 1996, pp. 1003-1005
Citations number
8
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Zeitschrift fur anorganische und allgemeine Chemie
ISSN journal
00442313 → ACNP
Volume
622
Issue
6
Year of publication
1996
Pages
1003 - 1005
Database
ISI
SICI code
0044-2313(1996)622:6<1003:KRAC-D>2.0.ZU;2-#
Abstract
The compounds K3BiSe3, Rb3BiSe3, and Cs3BiSe3 were synthesized by heat ing mixtures of Bi2O3 and the respective alkalicarbonate in a stream o f hydrogen saturated by selenium at 850 degrees C. Thin crystals of th e compounds appear red in transmitted light. They crystallize isostruc tural with Na3AsS3, space group P2(1)3, lattice constants a = 9.771(5) Angstrom, a = 10.161(3) Angstrom, and a = 10.587(5) Angstrom for K3Bi Se3, Rb3BiSe3, and Cs3BiSe3, respectively. The Na3AsS3 structure type is a derivative of the Th3P4 structure type.