D. Vaknin, C-60-AMINE ADDUCTS AT THE AIR-WATER-INTERFACE - A NEW CLASS OF LANGMUIR MONOLAYERS, Physica. B, Condensed matter, 221(1-4), 1996, pp. 152-158
A new class of Langmuir monolayers consisting of amine derivatives of
the C-60 fullerene is presented. X-ray and neutron reflectivity measur
ements and surface pressure-molecular area isotherms of spread films o
f the fullerene-dodecylamine (C-60-[NH2(CH2)(2)CH11](5)) and of the fu
llerene-propylamine (C-60-[NH2(CH2)(2)CH3](12)) adducts indicate that
despite the lack of distinct amphiphilic character, these materials fo
rm homogeneous monomolecular layers at air-water interfaces.