We have measured the composition profile on an Fe/Cr superlattice usin
g glancing incidence X-ray reflectivity. Resonant reflectivity measure
ments were carried out by tuning the X-ray energy around the respectiv
e K-edge of Fe and Cr. We were able to obtain excellent fits to the da
ta and get consistent geometry and composition parameters from the ref
lectivity measurements at six different X-ray energies. We obtained va
luable information on the interface composition of the superlattice an
d observed also a slight variation in composition at the bottom and to
p interfaces. The information obtained using this method allows a dete
rmination of not only the electron density but also the composition pr
ofiles of the multilayers. This non-destructive technique is a promisi
ng tool for the determination of the chemical composition of thin film
.