A SIMPLE SINGLE-STEP SYNTHESIS OF [(TC3H3)-TC-99(CO)(12)] FROM [(TCO4)-TC-99](-) AND ITS X-RAY CRYSTAL-STRUCTURE - APPLICATION TO THE PRODUCTION OF NO-CARRIER ADDED [(RE3H3)-RE-188(CO)(12)]

Authors
ALBERTO R SCHIBLI R SCHUBIGER PA ABRAM U HUBENER R BERKE H KADEN TA
Citation
R. Alberto et al., A SIMPLE SINGLE-STEP SYNTHESIS OF [(TC3H3)-TC-99(CO)(12)] FROM [(TCO4)-TC-99](-) AND ITS X-RAY CRYSTAL-STRUCTURE - APPLICATION TO THE PRODUCTION OF NO-CARRIER ADDED [(RE3H3)-RE-188(CO)(12)], Chemical communications, (11), 1996, pp. 1291-1292
Citations number
25
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
11
Year of publication
1996
Pages
1291 - 1292
Database
ISI
SICI code
1359-7345(1996):11<1291:ASSSO[>2.0.ZU;2-S
Abstract
Reduction of no-carrier added [(ReO4)-Re-188](-) (ng range) in thf-[NB u(4)]Cl with BH3 . thf under an atmosphere of CO yields [(ReCl3)-Re-18 8(CO)(3)](2-) and [Re-188(3)(mu-H)(3)(CO)(12)]; under similar conditio ns as with [(ReO4)-Re-188](-), the first mu-hydrido-bridged Tc-99 hydr ide carbonyl complex is prepared and structurally characterised.