OBSERVATION OF CO-METAL HYBRIDIZATION IN NI 2P X-RAY-ABSORPTION AND X-RAY-PHOTOEMISSION SPECTRA

Authors
HERNNAS B BJORNEHOLM O NILSSON A TILLBORG H SANDELL A MARTENSSON N KAROLEWSKI M ANDERSEN JN
Citation
B. Hernnas et al., OBSERVATION OF CO-METAL HYBRIDIZATION IN NI 2P X-RAY-ABSORPTION AND X-RAY-PHOTOEMISSION SPECTRA, Physical review. B, Condensed matter, 47(23), 1993, pp. 16052-16055
Citations number
14
Categorie Soggetti
Physics, Condensed Matter
Journal title
Physical review. B, Condensed matter → ACNP
ISSN journal
01631829
Volume
47
Issue
23
Year of publication
1993
Pages
16052 - 16055
Database
ISI
SICI code
0163-1829(1993)47:23<16052:OOCHIN>2.0.ZU;2-1
Abstract
The adsorption of CO has been studied on a Ni monolayer on Cu(100). Th e change in the Ni surface electronic structure upon CO adsorption is manifested in a broadening and appearance of new states in the Ni 2p x -ray absorption spectra. From a comparison with inverse photoemission spectra these states can be described as Ni 3d-CO 2pi hybrids. The Ni -CO hybridization is also seen to perturb the multiplets in the 2p(5)3 d9 photoemission satellite.