1-NAPHTHOIC ACID - A NEW-TYPE OF ASYMMETRIC CHROMOPHORE FOR EXCITON-COUPLED CIRCULAR-DICHROISM (ECCD)

Authors
SCHREDER B LUKACS Z SCHMITT M SCHREIER P HUMPF HU
Citation
B. Schreder et al., 1-NAPHTHOIC ACID - A NEW-TYPE OF ASYMMETRIC CHROMOPHORE FOR EXCITON-COUPLED CIRCULAR-DICHROISM (ECCD), Tetrahedron : asymmetry, 7(6), 1996, pp. 1543-1546
Citations number
10
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear","Chemistry Physical
Journal title
Tetrahedron : asymmetry → ACNP
ISSN journal
09574166
Volume
7
Issue
6
Year of publication
1996
Pages
1543 - 1546
Database
ISI
SICI code
0957-4166(1996)7:6<1543:1A-ANO>2.0.ZU;2-W
Abstract
1-Naphthoic acid was used for the first time as a new type of asymmetr ic chromophore for exciton coupled circular dichroism (ECCD). The UV a nd CD spectra of 13(S)-hydroxy-9(Z),11(E)-octadecadienoic acid methyle ster 1 derivatized with 1-naphthoic acid are presented and the CD data are compared with the corresponding 2-naphthoate and benzoate derivat ives. 1-Naphthoic acid represents a new type of asymmetric ECCD chromo phore which is useful for induced chirality. (C) 1996 Elsevier Science Ltd