ASYMMETRIC HYDROFORMYLATION OF STYRENE USING A RHODIUM CATALYST WITH BDPP AS THE CHIRAL LIGAND

Authors
MASDEUBULTO AM OREJON A CASTELLANOS A CASTILLON S CLAVER C
Citation
Am. Masdeubulto et al., ASYMMETRIC HYDROFORMYLATION OF STYRENE USING A RHODIUM CATALYST WITH BDPP AS THE CHIRAL LIGAND, Tetrahedron : asymmetry, 7(6), 1996, pp. 1829-1834
Citations number
18
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear","Chemistry Physical
Journal title
Tetrahedron : asymmetry → ACNP
ISSN journal
09574166
Volume
7
Issue
6
Year of publication
1996
Pages
1829 - 1834
Database
ISI
SICI code
0957-4166(1996)7:6<1829:AHOSUA>2.0.ZU;2-T
Abstract
Asymmetric hydroformylation of styrene is performed using the availabl e rhodium [Rh(mu-OMe)(COD)](2) complex with BDPP as the chiral auxilia ry ligand, The enantiomeric excesses observed heavily depend on the ex cess of diphosphine used and ee's of up to 60 % are achieved. The infl uence of different P and T conditions is also discussed. Copyright (C) 1996 Elsevier Science Ltd