THERMOCHEMISTRY AND ENERGETICS OF THE GASEOUS TETRABROMOPHOSPHONIUM CATION, CATION, PBR4+

Authors
JENKINS HDB
Citation
Hdb. Jenkins, THERMOCHEMISTRY AND ENERGETICS OF THE GASEOUS TETRABROMOPHOSPHONIUM CATION, CATION, PBR4+, Polyhedron, 15(17), 1996, pp. 2831-2834
Citations number
19
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
15
Issue
17
Year of publication
1996
Pages
2831 - 2834
Database
ISI
SICI code
0277-5387(1996)15:17<2831:TAEOTG>2.0.ZU;2-J
Abstract
The total lattice potential energy of phosphorus(V) bromide, [PBr4]Br- +(-), is reported to be 528.7+/-5 kJ mol(-1) as calculated from LATEN and the enthalpy of formation of the tetrabromophosphonium cation, Del ta(f)H(0)(PBr4+,g) is 479+/-5 kJ mol(-1). The homolytic bond energy of P-Br is found to be 326+/-5 kJ mol(-1). (C) 1996 Elsevier Science Ltd .