COORDINATION CHEMISTRY OF SCANDIUM .1. SYNTHESIS AND CRYSTAL-STRUCTURE OF SCANDIUM 6-COORDINATE GLYCINE COMPLEX [SC-2(GLY)(6)(CLO4)(6)](N)

Authors
YAN CH ZHANG YW LI BG JIN TZ XU GG
Citation
Ch. Yan et al., COORDINATION CHEMISTRY OF SCANDIUM .1. SYNTHESIS AND CRYSTAL-STRUCTURE OF SCANDIUM 6-COORDINATE GLYCINE COMPLEX [SC-2(GLY)(6)(CLO4)(6)](N), Polyhedron, 15(17), 1996, pp. 2895-2899
Citations number
18
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
15
Issue
17
Year of publication
1996
Pages
2895 - 2899
Database
ISI
SICI code
0277-5387(1996)15:17<2895:CCOS.S>2.0.ZU;2-H
Abstract
The title complex was synthesized in an aqueous solution of Sc(ClO4)(3 ), and its crystal structure was determined by an X-ray diffraction me thod. The complex has an infinite chain structure, built from dimeric units. Two scandium ions are combined by three simple bridging carboxy l groups from three glycine molecules. Only one type of bonding mode o f the carboxyl groups is represented. Scandium exhibits an octahedral configuration. (C) 1996 Elsevier Science Ltd.