SURFACE-ACTIVITY OF A BORON-NITRIDE POWDER - A VIBRATIONAL STUDY

Citation
Mi. Baraton et al., SURFACE-ACTIVITY OF A BORON-NITRIDE POWDER - A VIBRATIONAL STUDY, Langmuir, 9(6), 1993, pp. 1486-1491
Citations number
34
Categorie Soggetti
Chemistry Physical
Journal title
ISSN journal
07437463
Volume
9
Issue
6
Year of publication
1993
Pages
1486 - 1491
Database
ISI
SICI code
0743-7463(1993)9:6<1486:SOABP->2.0.ZU;2-L
Abstract
The surface of a turbostratic BN powder has been characterized by FT-I R spectrometry. BOH, BNH2, and B2NH species revealing a hydrolyzed sur face are identified and the activity of the surface is evidenced by di ethyl ether dissociation and acetonitrile polymerization. Other change s in BN surface spectrum by probe-molecule addition are also proposed to be due to an intercalation process.