REMOTE ASYMMETRIC INDUCTION IN ORGANOCOPPER CONJUGATE ADDITIONS TO 3-KETOACRYLATES

Authors
CAPTAIN LF XIA XY LIOTTA DC
Citation
Lf. Captain et al., REMOTE ASYMMETRIC INDUCTION IN ORGANOCOPPER CONJUGATE ADDITIONS TO 3-KETOACRYLATES, Tetrahedron letters, 37(25), 1996, pp. 4293-4296
Citations number
23
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
37
Issue
25
Year of publication
1996
Pages
4293 - 4296
Database
ISI
SICI code
0040-4039(1996)37:25<4293:RAIIOC>2.0.ZU;2-4
Abstract
Remote asymmetric induction has been achieved in the conjugate additio n of organocopper reagents to a novel 3-ketoacrylate system, 1. Conjug ate additions proceed in moderate to good yield and with high regio- a nd scereoselectivity in the presence of diethylaluminum chloride. Copy right (C) 1996 Elsevier Science Ltd.