PALLADIUM-CATALYZED REDUCTIVE CYCLIZATION REACTION IN ALKALOID SYNTHESIS - AN ENANTIOSELECTIVE TOTAL SYNTHETIC ROUTE TO (-PUMILIOTOXIN-C())

Authors
TOYOTA M ASOH T FUKUMOTO K
Citation
M. Toyota et al., PALLADIUM-CATALYZED REDUCTIVE CYCLIZATION REACTION IN ALKALOID SYNTHESIS - AN ENANTIOSELECTIVE TOTAL SYNTHETIC ROUTE TO (-PUMILIOTOXIN-C()), Tetrahedron letters, 37(25), 1996, pp. 4401-4404
Citations number
27
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
37
Issue
25
Year of publication
1996
Pages
4401 - 4404
Database
ISI
SICI code
0040-4039(1996)37:25<4401:PRCRIA>2.0.ZU;2-A
Abstract
Beginning with the chirally homogeneous cyclohexenol 3, an enantiosele ctive total synthetic route to (+)-pumiliotoxin C (1) has been describ ed. Palladium catalyzed reductive cyclization reaction was employed to prepare a key component in the synthesis. Copyright (C) 1996 Elsevier Science Ltd