METAL POLYPYRAZOLYLBORATES .10. THIENYLMERCURY(II) DERIVATIVES - THE X-RAY CRYSTAL-STRUCTURE OF [(5-ME)THIEN-2-YL]HG-(MU-PZ)(2)B(PZ)(2)

Authors
LOBBIA GG CECCHI P GIORDANO F SANTINI C
Citation
Gg. Lobbia et al., METAL POLYPYRAZOLYLBORATES .10. THIENYLMERCURY(II) DERIVATIVES - THE X-RAY CRYSTAL-STRUCTURE OF [(5-ME)THIEN-2-YL]HG-(MU-PZ)(2)B(PZ)(2), Journal of organometallic chemistry, 515(1-2), 1996, pp. 213-220
Citations number
28
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
515
Issue
1-2
Year of publication
1996
Pages
213 - 220
Database
ISI
SICI code
0022-328X(1996)515:1-2<213:MP.TD->2.0.ZU;2-H
Abstract
Thienylmercury(II) polypyrazolylborates (Tp = hydridotris-(3,5-dimeth ylpyrazol-1-yl)borato, Tp(Me) = hydridotris(3-methylpyrazol-1-yl)borat o, pzTp = tetrakis(pyrazol-1-yl)borato) have been synthesised and char acterised through elemental analysis, electrical conductivity, molecul ar weights, and spectral measurements (IR in the solid state and H-1, C-13, Hg-199 NMR in solution), The structure of [(5-Me)Thien-2-yl]Hg-( mu-Pz)(2)B(Pz)(2) has been determined (Pbcn; a = 22.530(6), b = 9.366( 4), c = 19.310(5) Angstrom; Z = 8; R = 0.054). The mercury(II) atom is tricoordinated in an approximately planar 'T-shaped' configuration.