MODIFICATION REACTIONS ON POLYPHENYLSILYN E AND BRANCHED POLYSILANES

Authors
UHLIG W
Citation
W. Uhlig, MODIFICATION REACTIONS ON POLYPHENYLSILYN E AND BRANCHED POLYSILANES, Journal of organometallic chemistry, 516(1-2), 1996, pp. 147-154
Citations number
30
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
516
Issue
1-2
Year of publication
1996
Pages
147 - 154
Database
ISI
SICI code
0022-328X(1996)516:1-2<147:MROPEA>2.0.ZU;2-P
Abstract
Polyphenylsilyne and branched copolysilanes have been prepared via red uctive coupling of the corresponding organochlorosilanes with potassiu m-graphite. Reaction of these polymers with trifluoromethanesulfonic a cid lead to triflate substituted polymers. These compounds are modifie d by following reactions with nucleophiles, LiAlH4, or C8K. The simple syntheses allow variation of the properties of the preceramic polymer s (molecular weights, solubility, content of carbon, functional groups ). The polymers are characterized by Si-29 NMR spectroscopy.