ORGANOMETALLIC CLUSTER COMPLEXES WITH FACE-CAPPING ARENE LIGANDS .7. NUCLEOPHILIC-SUBSTITUTION OF FLUORIDE IN A FACIALLY COORDINATED ARENE LIGAND

Authors
WADEPOHL H BORCHERT T PRITZKOW H
Citation
H. Wadepohl et al., ORGANOMETALLIC CLUSTER COMPLEXES WITH FACE-CAPPING ARENE LIGANDS .7. NUCLEOPHILIC-SUBSTITUTION OF FLUORIDE IN A FACIALLY COORDINATED ARENE LIGAND, Journal of organometallic chemistry, 516(1-2), 1996, pp. 187-189
Citations number
26
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
516
Issue
1-2
Year of publication
1996
Pages
187 - 189
Database
ISI
SICI code
0022-328X(1996)516:1-2<187:OCCWFA>2.0.ZU;2-9
Abstract
Reaction of p-fluoro-alpha-methylstyrene with [(eta-C5H5)Co(eta-C(6)Me (6))] leads to the cluster complex ta(2):eta(2):eta(2)-p-fluoro-alpha- methylstyrene)] 1b. Nucleophilic substitution of fluoride by H- or Ph( -) takes place when Ib is treated with LiHBEt(3) or PhLi.