REACTIONS OF ORTHOMANGANATED ARYL KETONES WITH PHNSO AND RELATED SPECIES - A NEW ROUTE TO ORTHOMANGANATED IMINES

Citation
Jm. Cooney et al., REACTIONS OF ORTHOMANGANATED ARYL KETONES WITH PHNSO AND RELATED SPECIES - A NEW ROUTE TO ORTHOMANGANATED IMINES, Journal of organometallic chemistry, 516(1-2), 1996, pp. 191-197
Citations number
30
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
ISSN journal
0022328X
Volume
516
Issue
1-2
Year of publication
1996
Pages
191 - 197
Database
ISI
SICI code
0022-328X(1996)516:1-2<191:ROOAKW>2.0.ZU;2-U
Abstract
PhN=S=O reacts with some orthomanganated acetophenones to replace the ketone oxygen with a Ph-N group, so generating the corresponding ortho manganated imine. No insertion into the Mn-C bond was observed, in con trast to analogous reactions of SO2. The related PhS(O)(2)N=S=O or (Ph S(O)(2)N=)(2)S did not react under the same conditions. The X-ray crys tal structure of one of the new imine complexes, (N-phenylimino)ethyl] phenyltetracarbonylmanganese, was determined.