Cj. Uchibori et al., EFFECTS OF DEPOSITION SEQUENCE ON ELECTRICAL-PROPERTIES OF INAS-NI-W OHMIC CONTACTS TO N-TYPE GAAS, Materials transactions, JIM, 37(4), 1996, pp. 670-675
The effects of the deposition sequences on the formation mechanism of
the InAs-Ni-W contacts were investigated by analyzing the interfacial
structure using x-ray diffraction and transmission electron microscopy
and by measuring the contact resistances using a transmission line me
thod. Ni atoms in the Ni/InAs/W contacts (where a slash sign (/) indic
ates the deposition sequence) diffused into the GaAs substrate during
annealing at temperatures below 300 degrees C, and formed NiAs compoun
ds on the GaAs surface after subsequent annealing at high temperatures
. In this contacts, the total InxGa1-xAs area contacting the GaAs surf
ace was small, resulting in high contact resistances. Ni atoms in the
InAs/Ni/W contacts broke the compositional stoichiometry of the InAs l
ayer during annealing at low temperatures, and enhanced the reaction b
etween the InAs and the GaAs upon annealing at higher temperatures. In
this contacts, a large area of the GaAs surface was observed to be co
vered by the InxGa1-xAs layers, resulting in relatively low contact re
sistances. The effective barrier to limit the current flow would be th
e barrier at the InxGa1-xAs/GaAs interface which was simulated to be 2
.1x10(-20) J (0.13eV) by analyzing the temperature dependence of the c
ontact resistances.