S. Adhikari et al., ADIABATIC SWITCHING IN TIME-DEPENDENT FOURIER GRID HAMILTONIAN METHOD- SOME TEST CASES, Chemical physics, 206(3), 1996, pp. 315-324
Adiabatically switched time-dependent Fourier grid Hamiltonian methods
in one and many dimensions are proposed and tested. The method encoun
ters no difficulty even in the presence of tunneling, level crossings
and can handle fairly large changes or distortions in the Hamiltonian.
The specific eigenstate is obtained as the limit of a continuous succ
ession of eigenstates of a slowly changing H(t), the t = 0 and t = T (
large) limits of which are well defined. Important features of the met
hod are analysed with particular reference to the adiabatic passage of
an eigenstate of (a) a harmonic oscillator to the corresponding eigen
state of a forced harmonic oscillator, (b) a harmonic oscillator to an
appropriate eigenstate of a symmetric or an asymmetric double well Ha
miltonian, (c) a Morse oscillator to that of a double well Hamiltonian
, and (d) a two-dimensional harmonic oscillator to the appropriate eig
enstate of a Henon-Heiles system.