S. Ried et al., ELECTROCONVECTIVE INSTABILITIES IN SMECTIC-C-ASTERISK LIQUID-CRYSTAL FILMS, Physical review. E, Statistical physics, plasmas, fluids, and related interdisciplinary topics, 53(6), 1996, pp. 6101-6114
We investigate the onset of electroconvection in freely suspended smec
tic-C (Sm-C*) liquid crystal films. Compared to nematic liquid crysta
ls the Sm-C phase shows in addition a macroscopic electric polarizati
on within the smectic planes. Describing the Sm-C film by a two-dimen
sional theory we find for low and high frequencies of the applied elec
tric ac held, respectively, a conductive and a dielectric instability
regime, similar to the case of electroconvection in nematic liquid cry
stals. Because of the polarization in the Sm-C phase an additional, '
'subharmonic regime'' appears at intermediate frequencies, where all t
he hydrodynamic and electric variables are moving with half the freque
ncy of the applied ac voltage at the onset of convection. For some spe
cial but experimentally accessible values of material parameters, geom
etric dimensions, and ac voltage frequency also a codimension-three po
int is found, where the threshold voltages of all three possible regim
es coincide. For de voltages the generalized Frederiks transition is p
resented and discussed as far as it restricts the observation of patte
rn forming convective instabilities. Both types of instabilities are i
nvestigated for de voltages to get a fundamental insight into the mech
anisms involved as well as for ac voltages to stimulate experiments.