M. Slemrod, METASTABLE FLUID-FLOW DESCRIBED VIA A DISCRETE-VELOCITY COAGULATION-FRAGMENTATION MODEL, Journal of statistical physics, 83(5-6), 1996, pp. 1067-1108
A discrete-velocity Boltzmann model is introduced. It is based on two
principles: (i) clusters of particles move in R(3) with seven fixed mo
menta; (ii) clusters may gain or lose particles according to the rules
of Becker-Db;ring cluster equations. The model provides a kinetic rep
resentation of evaporation and condensation. The model is used to obta
in macroscopic fluid equations which are valid into the metastable flu
id regime, 0 less than or equal to rho < rho(s) + O(mu(sigma)), where
sigma is any positive number, mu is the inelastic Knudsen number, and
rho(s) is the saturation density.