Xj. Bao et Lr. Dix, SMECTIC PHASES OBSERVED IN 1,1,2,2,-TETRAHYDROPERFLUOROALKYL-4-NITROBENZOATES, Molecular crystals and liquid crystals science and technology. Section A, Molecular crystals and liquid crystals, 281, 1996, pp. 291-294
On studying the thermal behaviour of a series of 1,1,2,2-tetrahydro-pe
rfluoroalkyl 4-nitrobenzoates it was found that the decyl and dodecyl
compounds showed smectic mesophases. This illustrates that a polar sub
stituent in the 3-position of the aromatic ring for 1,1,2,2-tetrahydro
perfluoroalkylbenzoates is not a requirement for thermotropic behaviou
r.