DIRECT OBSERVATION OF HYDROGEN-DEUTERIUM EXCHANGE-REACTION IN COBALOXIME CRYSTAL BY NEUTRON-DIFFRACTION

Authors
OHGO Y OHASHI Y KLOOSTER WT KOETZLE TF
Citation
Y. Ohgo et al., DIRECT OBSERVATION OF HYDROGEN-DEUTERIUM EXCHANGE-REACTION IN COBALOXIME CRYSTAL BY NEUTRON-DIFFRACTION, Chemistry Letters, (6), 1996, pp. 445-446
Citations number
9
Categorie Soggetti
Chemistry
Journal title
Chemistry Letters → ACNP
ISSN journal
03667022
Issue
6
Year of publication
1996
Pages
445 - 446
Database
ISI
SICI code
0366-7022(1996):6<445:DOOHEI>2.0.ZU;2-Q
Abstract
After a crystal of henylethylamine]bis(dimethylglyoximato)cobalt(III) was exposed to a xenon lamp for two weeks, its structure was analyzed by neutron diffraction. The deuterium atom was exchanged partially wit h one of the three methyl hydrogenes of the cyanoethyl group. The exch anged one is located closest to the deuterium atom.