COMPLEXATION KINETICS OF 5-OCTYLOXYMETHYL-8-QUINOLINOL WITH NI(II) ATTHE HEPTANE-WATER INTERFACE

Authors
SHIOYA T TSUKAHARA S TERAMAE N
Citation
T. Shioya et al., COMPLEXATION KINETICS OF 5-OCTYLOXYMETHYL-8-QUINOLINOL WITH NI(II) ATTHE HEPTANE-WATER INTERFACE, Chemistry Letters, (6), 1996, pp. 469-470
Citations number
10
Categorie Soggetti
Chemistry
Journal title
Chemistry Letters → ACNP
ISSN journal
03667022
Issue
6
Year of publication
1996
Pages
469 - 470
Database
ISI
SICI code
0366-7022(1996):6<469:CKO5WN>2.0.ZU;2-W
Abstract
Complexation kinetics of 5-octyloxymethyl-8-quinolinol (Hocqn) with Ni (II) at the heptane-water interface was studied by measuring the dynam ic interfacial tension. Decrease in the interfacial tension was caused by the adsorption of 1:1 complex formed at the interface. It was foun d that the complexation rate at the interface was 43 times faster than that in the bulk, and that the rate also depended on the counter-anio n in the aqueous phase.