Electron emission measurements on diamond films synthesized by chemica
l vapor deposition are reported. UV photoemission spectroscopy indicat
es that the samples exhibit a negative electron affinity after exposur
e to hydrogen plasma. Secondary electron emission yields vary from 2.2
to 9.2. Field emission current-voltage measurements indicate threshol
d voltages ranging from 28 to 84 V mu m(-1). The film with the highest
secondary yield also exhibits the lowest emission threshold.