Jp. Favier et al., COMPACT, OPEN AND GENERAL-PURPOSE CELL OF VARIABLE EFFECTIVE PATHLENGTH - DIRECT ABSORPTION MEASUREMENT OF SO42- IN WATER, Fresenius' journal of analytical chemistry, 355(3-4), 1996, pp. 357-358
The use of an optothermal window (OW) was proposed for the direct (no
need for sample preparation) spectroscopic, non-destructive measuremen
t of SO42- in water at 1078 cm(-1). The presently determined limit of
detection (LOD) of 1 mmol/L is comparable to that provided by CO2 lase
r photoacoustic spectroscopy, but about one order of magnitude superio
r to that obtainable by the ATR method.