SPECTROSCOPIC CHARACTERIZATION OF INORGANIC HOST-ORGANIC DOPANT FILMSFABRICATED VIA LASER-ASSISTED MOLECULAR-BEAM DEPOSITION

Thin films of hybrid inorganic:organic composites [TiO2:copper phthalo cyanine, Al2O3:6-propionyl-2-(dimethylamino)naphthalene, and Al2O3:rho damine 6G] were fabricated by mixing the constituents in the gas phase via the technique of laser-assisted molecular beam deposition. These films were characterized by UV-visible, infrared, and steady-state flu orescence spectroscopic techniques. UV-visible and infrared spectra of TiO2:copper phthalocyanine films indicate that the organometallic com pound, copper phthalocyanine, is trapped within the host TiO2 matrix w ithout degradation. The local microenvironment of the organic componen ts in these composite films were studied by steady state fluorescence spectroscopy. Emission spectra indicate that the organic dye molecule, rhodamine 6G, is trapped within the Al2O3 matrix as the monomer witho ut aggregation. The spectral red shift of the emission peak and the fu ll width at the half maximum suggest the environmentally sensitive pro be, 6-propionyl-2-(dimethylamino) naphthalene, molecules are embedded within the Al2O3 matrix as opposed to being adsorbed on the Al2O3 surf ace.